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The Zone System and in general every rule that matches the dynamic range of the capture medium and the maximum contrast of the scene tries to get two results: correlating the minimum and maximum points of subject contrast with the dynamic range/contrast index of the recording material and to record the maximum number of tones between these extremes. When working with black-and-white materials (Leica Monochrom and black-and-white silver emulsions) a third parameter is required: the spectral sensitivity of the material must equal the spectral sensitivity of the eye. This introduces a subjective factor, because every human will have a different perception of the brightness of colors.
http://www.imx.nl/photo/technique/styled–10/colorimetryM9.html